Silicon kerf loss recycling

Activity Code: ENV.2013.6.3-1
Project Reference: 603718
Coordinator:Helmholtz-Zentrum Dresden-Rossendorf

Description:

Solar energy direct conversion to electricity is expanding rapidly to satisfy the demand for renewable energy. The most efficient commercial photovoltaic solar cells are based on silicon. While the reuse of feedstock is a severe concern of the photovoltaic industry, up to 50% of the valuable resource is lost into sawdust during wafering. Presently, the majority of silicon ingots are sliced in thin wafers by LAS (loose abrasive sawing) using slurry of abrasive silicon carbide particles. The silicon carbide is not separable from the silicon dust in an economical way. The newer FAS (fixed abrasive sawing) uses diamond particles fixed to the cutting wire. It is expected that FAS will replace LAS almost completely by 2020 for poly/mono-crystalline wafering. The intention of the proposed project is to recycle the FAS loss aiming at a sustainable solution. The main problem is the large surface to volume ratio of micron size silicon particles in the kerf loss, leading to formation of SiO2 having a detrimental effect on the crystallisation. The compaction process developed by GARBO meets the requirements of a reasonable crucible-loading factor. Overheating the silicon melt locally in combination with optimised electromagnetic stirring provides the means to remove SiO2. The technology developed by GARBO removes the organic binding agents, leaving about 200 ppm wt diamond particle contamination. If untreated, the carbon level is above the solubility limit. Formation of silicon carbide and precipitation during crystallisation is to be expected. The electromagnetic mixing, in combination with the effective means to separate electrically non-conducting silicon carbide and remaining SiO2 particles from the silicon melt by Leenov-Kolin forces and the control of the solidification front, is the proposed route to produce the solar grade multi-crystalline silicon blocks cast in commercial size in a unified process.

Partners:

• Universita Degli Studi Di Padova, Italia
• Elektrische Automatisierungs- und Antriebstechnik Eaat Gmbh Chemnitz, Deutschland
• Garbo Srl, Italia
• University Of Greenwich, United Kingdom